Upload a UBL/XML invoice to find out whether it passes the technical checks before you send it to your customer. If it fails, you get the rule, the line in the XML and a concrete fix. Validation is free to use and needs no registration.
The validator calls the same validation service (ion-docval) that ePošťák uses to check documents passing through the Peppol network. The result is therefore the same as the one your recipient's access point would see.
Three worked examples of validation errors with the fix. Each includes a downloadable XML, the error code and the result of re-validation. The article is in Slovak.
Even a technically valid invoice will not be delivered if the recipient is not registered on the Peppol network or its identifier does not match the address in the invoice. Look it up in the directory, or test the whole sending flow from your ERP.